How do I do 46 acrid solution

46. ​​Basic inorganic solid substances and mixtures of these substances (such as preparations, preparations and wastes) that cannot be assigned to another collective name:

  1. 3262 Corrosive solid, basic, inorganic, n.o.s.;
  2. 3262 Corrosive solid, basic, inorganic, n.o.s.;
  3. 3262 Corrosive solid, basic, inorganic, n.o.s.

47.Basic, inorganic liquid substances as well as solutions and mixtures of these substances (such as preparations, preparations and wastes) that cannot be assigned to another collective name:

  1. 3266 Corrosive, basic, inorganic liquid, n.o.s.;
  2. 3266 Corrosive, basic, inorganic liquid, n.o.s.;
  3. 3266 Corrosive liquid, basic, inorganic, n.o.s.

Organic substance

51. Tetraalkylammonium hydroxides:

  1. 1835 tetramethylammonium hydroxide.

52.Solid amines and polyamines:

  1. 3259 amines, solid, corrosive, n.o.s. or

    3259 polyamines, solid, corrosive, n.o.s.;

  2. 3259 amines, solid, corrosive, n.o.s. or

    3259 polyamines, solid, corrosive, n.o.s.;

  3. 2280 hexamethylenediamine, solid, 2579 piperazine (diethylenediamine),

    3259 amines, solid, corrosive, n.o.s. or

    3259 polyamines, solid, corrosive, n.o.s.

53. Liquid amines and polyamines or alkanolamines, highly corrosive or corrosive, with a flash point above 61 ° C:

  1. 2735 amines, liquid, corrosive, n.o.s. or

    2735 polyamines, liquid, corrosive, n.o.s.;

  2. 1761 copper ethylenediamine, solution, 1783 hexamethylenediamine, solution, 2079 diethylenetriamine, 2259 triethylenetetramine,

    2735 amines, liquid, corrosive, n.o.s. or

    2735 polyamines, liquid, corrosive, n.o.s.;

  3. 1761 copper ethylenediamine, solution, 1783 hexamethylenediamine, solution, 2269 3,3'-iminobispropylamine (dipropylenetriamine), 2289 isophoronediamine, 2320 tetraethylene pentamine, 2326 trimethylcyclohexylamine, 2327 trimethylhexamethylenediamine, 2491 ethanolamine, aminohexylamine 3055 2- (2-Aminoethoxy) ethanol, 2735 amines, liquid, corrosive, nos or

    2735 polyamines, liquid, corrosive, n.o.s.

54. Liquid amines and polyamines, highly corrosive or corrosive, flammable, with a boiling point above 35 ° C:

  1. 2401 piperidine;

    2734 amines, liquid, corrosive, flammable, n.o.s. or

    2734 polyamines, liquid, corrosive, flammable, n.o.s.;

  2. 1604 ethylenediamine, 2051 2-dimethylaminoethanol, 2248 di-n-butylamine, 2258 1,2-propylenediamine, 2264 N, N-dimethylcyclohexylamine, 2357 cyclohexylamine, 2619 benzyldimethylamine, 2685 N, N-diethylethylenediamine, 2686 2-diethylaminoethanol

    2734 amines, liquid, corrosive, flammable, n.o.s. or

    2734 polyamines, liquid, corrosive, flammable, n.o.s.

55. Basic organic solid substances and mixtures of these substances (such as preparations, preparations and wastes) that cannot be assigned to another collective name:

  1. 3263 Corrosive solid, basic, organic, n.o.s.;
  2. 3263 Corrosive solid, basic, organic, n.o.s.;
  3. 3263 Corrosive solid, basic, organic, n.o.s.

56.Basic organic liquid substances as well as solutions and mixtures of these substances (such as preparations, preparations and wastes) that cannot be assigned to another collective name:

  1. 3267 Corrosive liquid, basic, organic, n.o.s.;
  2. 3267 Corrosive liquid, basic, organic, n.o.s.;
  3. 3267 Corrosive liquid, basic, organic, n.o.s.

C. Other corrosive substances

61. Chlorite and hypochlorite solutions:

  1. 1791 hypochlorite solution, 1908 chlorite solution
  2. 1791 hypochlorite solution, 1908 chlorite solution.

    Note Solid chlorites and hypochlorites are substances of Class 5.1 (see marginal 2501 items 14, 15 and 29).

62. Chlorophenolates and phenolates:

  1. 2904 chlorophenolate, liquid or 2904 phenolate, liquid, 2905 chlorophenolate, solid or 2905 phenolate, solid.

63. Formaldehyde solutions:

  1. 2209 Formaldehyde solution, with at least 25% formaldehyde.

Note

  1. 1198 formaldehyde solution, flammable, is a substance of class 3 [see marginal 2301 number 33 c)]
  2. Formaldehyde solutions, non-flammable, with less than 25% formaldehyde are not subject to ADR regulations.

64. Chloroformates and chlorothioformates:

  1. 1739 benzyl chloroformate;
  2. 2826 ethyl chlorothioformate.
Note Chloroformates with predominantly toxic properties are substances of Class 6.1 (see marginal 2601 numbers 10, 17, 27 and 28).

65. Corrosive solid substances and mixtures of these substances (such as preparations, preparations and wastes) which cannot be assigned to another collective name:

  1. 3147 dye, solid, corrosive, n.o.s. or 3147 intermediate dye, solid, corrosive, n.o.s.

    1759 Corrosive solid, na g .;

  2. 1770 diphenyl bromomethane,

    3147 dye, solid, corrosive, n.o.s. or

    3147 intermediate dye, solid, corrosive, n.o.s.,

    3244 Solids with corrosive liquid, n.o.s.;

    1759 Corrosive solid, n.o.s.,

Note Mixtures of solid substances, which are not subject to the provisions of ADR, with corrosive liquids may be carried under the identification number 3244 without first applying the classification criteria of marginal 2800 (3), provided that at the time of loading the substance or the No excess liquid is visible when the packaging or the transport unit is closed. Each packaging must be of a type that has successfully passed a leak test for packaging group II.
  1. 2803 gallium,

    3147 dye, solid, corrosive, n.o.s. or

    3147 intermediate dye, solid, corrosive, n.o.s.

    1759 Corrosive solid, n.o.s.,

    Note Special packing conditions exist for 2803 gallium [see marginal 2807 (4)].

66. Corrosive liquid substances as well as solutions and mixtures of these substances (such as preparations, preparations and wastes) that cannot be assigned to another collective name:

  1. 1760 Corrosive liquid, n.o.s.,

    1903 disinfectant, liquid, corrosive, n.o.s.;

    2801 dye, liquid, corrosive, n.o.s. or

    2801 intermediate dye, liquid, corrosive, n.o.s.

  2. 2226 benzotrichloride (trichloromethylbenzene), 2705 1-pentol (3-methylpen-2-th-4-in-1 -01), 3066 paint (including paint, varnish, enamel, stain, shellac, varnish, polish and liquid base lacquer) or 3066 paint accessories (including paint thinner and remover components),

    1760 Corrosive liquid, n.o.s.,

    1903 disinfectant, liquid, corrosive, n.o.s.,

    2801 dye, liquid, corrosive, n.o.s. or

    2801 intermediate dye, liquid, corrosive, n.o.s.;

  3. 2809 mercury, 3066 paint (including paint, varnish, enamel, stain, shellac, varnish, polish and liquid base lacquer) or 3066 paint accessories (including paint thinner and remover components),

    1760 Corrosive liquid, n.o.s.,

    1903 disinfectant, liquid, corrosive, n.o.s.,

    2801 dye, liquid, corrosive, n.o.s. or

    2801 intermediate dye product, liquid, corrosive, n.o.s.

    Note

    1. Special packing provisions exist for 2809 mercury (see marginal 2807 (4)].
    2. A substance named under a different number of the ADR may not be carried under the entries 3066 paint or 3066 paint accessories. Substances carried under these entries may contain 20% or less nitrocellulose, provided that the nitrocellulose does not contain more than 12.6% nitrogen.

67. Corrosive solid substances and mixtures of these substances (such as preparations, preparations and wastes), flammable, which cannot be assigned to another collective name:

  1. 2921 Corrosive solid, flammable, n.o.s.;
  2. 2921 Corrosive solid, flammable, n.o.s.

68. Corrosive liquid substances as well as solutions and mixtures of these substances (such as preparations, preparations and waste), flammable, with a boiling point above 35 ° C which cannot be assigned to another collective name:

  1. 2920 Corrosive liquid, flammable, n.o.s.;
  2. 2920 Corrosive liquid, flammable, n.o.s.

69. Corrosive solid substances and mixtures of these substances (such as preparations, preparations and waste), capable of self-heating, which cannot be assigned to another collective name:

  1. 3095 Corrosive solid, self-heating, n.o.s.;
  2. 3095 Corrosive solid, self-heating, n.o.s.

70. Corrosive liquid substances as well as solutions and mixtures of these substances (such as preparations, preparations and waste), capable of self-heating, which cannot be assigned to another collective name:

  1. 3301 Corrosive liquid, self-heating, n.o.s.;
  2. 3301 Corrosive liquid, self-heating, n.o.s.

71. Corrosive solid substances and mixtures of these substances (such as preparations, preparations and wastes) which, in contact with water, emit flammable gases and which cannot be assigned to another collective name:

  1. 3096 Corrosive solid, water reactive, n.o.s.;
  2. 3096 Corrosive solid, water reactive, n.o.s.
Note The term "water-reactive" refers to a substance which, in contact with water, emits flammable gases.

72. Corrosive liquid substances as well as solutions and mixtures of these substances (such as preparations, preparations and wastes) which develop flammable gases in contact with water and which cannot be assigned to another collective name:

  1. 3094 Corrosive liquid, reactive with water, n.o.s.;
  2. 3094 Corrosive liquid, reactive with water, n.o.s.
Note The term "reactive with water" describes a substance which, in contact with water, emits flammable gases.

73. Corrosive solid substances and mixtures of these substances (such as preparations, preparations and waste), with an inflammatory (oxidizing) effect, which cannot be assigned to another collective name:

  1. 3084 Corrosive solid, oxidizing, n.o.s.;
  2. 3084 Corrosive solid, oxidizing, n.o.s.

74. Corrosive liquid substances as well as solutions and mixtures of these substances (such as preparations, preparations and waste), with an inflammatory (oxidizing) effect, which cannot be assigned to another collective name:

  1. 3093 Corrosive liquid, inflammatory (oxidizing) effect, n.o.s.;
  2. 3093 Corrosive liquid, oxidizing, n.o.s.

75. Corrosive solid substances and mixtures of these substances (such as preparations, preparations and wastes), toxic, which cannot be assigned to another collective name:

  1. 2923 Corrosive solid, toxic, n.o.s.;
  2. 2923 Corrosive solid, toxic, n.o.s.;
  3. 2923 Corrosive solid, toxic, n.o.s.

76. Corrosive liquid substances as well as solutions and mixtures of these substances (such as preparations, preparations and wastes), toxic, which cannot be assigned to another collective name:

  1. 2922 Corrosive liquid, toxic, n.o.s.;
  2. 2922 Corrosive liquid, toxic, n.o.s.;
  3. 2922 Corrosive liquid, toxic, n.o.s.

D. Objects that contain corrosive substances

81.Batteries:

  1. 2794 batteries (accumulators), wet, filled with acid, electrical collectors, 2795 batteries (accumulators), wet, filled with alkalis, electrical collectors, 2800 batteries (accumulators), wet, leak-proof, electrical collectors, 3028 batteries (accumulators), dry , Potassium hydroxide, solid, containing, electrical collectors.

    Note

    1. There are special packaging provisions for these items [see marginal 2807 (5)].
    2. Batteries (with identification number 2800) are considered leak-proof if they withstand the vibration and pressure test specified below without any loss of fluid.
      Vibration test: The battery is clamped onto the test plate of a vibration device and subjected to a simple sinusoidal movement with an amplitude of 0.8 mm (1.6 mm total deflection).
      The frequency is changed in steps of 1 Hz / min between 10 Hz and 55 Hz. The entire range of frequencies is passed through in both directions in 95 ± 5 minutes for each mounting position (direction of vibration) of the battery. The battery is tested in three mutually perpendicular positions (including a position in which the filling and ventilation openings, if any, are inverted) for periods of equal duration.
      Pressure test: Following the vibration test, the battery is subjected to a pressure difference of at least 88 kPa at 24 ° C ± 4 ° C for six hours. The battery is tested in three mutually perpendicular positions (including a position with the fill and vent holes, if any, inverted) for a minimum of six hours each.

82. Other objects containing corrosive substances:

  1. 1774 fire extinguisher charges, corrosive liquid, 2028 smoke bombs, smoke bombs, non-explosive, which contain a corrosive liquid, without detonators.

E. Empty packaging

91. Uncleaned empty packaging, including empty IBCs, empty tank vehicles, empty demountable tanks, empty tank-containers and empty vehicles and empty small containers for goods in bulk which have contained substances of Class 8.

Note Uncleaned empty packaging, including empty bulk containers (IBC), which have contained substances of this class, are not subject to the provisions of ADR if suitable measures have been taken to exclude possible hazards. Hazards are excluded if measures to eliminate the hazards of classes 1 to 9 have been taken.

2801a

With the exception of the provisions mentioned in paragraph (6), the provisions contained in this Appendix and Appendix B for this class are not subject to:

(1) Substances of numbers 1 to 5, 7 to 13, 16, 17, 31 to 47, 51 to 56 and 61 to 76, which are carried under the following conditions:

  1. Substances that fall under a) of the individual numbers:
    • liquid substances up to 100 ml per inner packaging and 400 ml per package;
    • solid materials up to 500 g per inner packaging and 2 kg per package;
  2. Substances that fall under b) of the individual numbers:
    • liquid substances up to 1 liter per inner packaging and 4 liters per package;
    • solid materials up to 3 kg per inner packaging and 12 kg per package;
  3. Substances that fall under c) of the individual numbers:
    • liquid substances up to 3 liters per inner packaging and 12 liters per package;
    • solid materials up to 6 kg per inner packaging and 24 kg per package.

These quantities of substance must be transported in composite packagings which at least meet the requirements of marginal 3538.

The "General Packaging Instructions" of marginal 3500 (1), (2) and (5) to (7) must be observed.

(2) Substances of numbers 1 to 5, 7 to 13, 16, 17, 31 to 47, 51 to 56 and 61 to 76, which are contained in inner packaging made of metal or plastic, which are not prone to breakage or can be easily punctured and are transported in trays with stretch or shrink film instead of outer packaging under the following conditions:

  1. Liquid substances that fall under b) of the individual numbers: up to 500 ml per inner packaging and up to 4 liters per package;
  2. solid substances falling under b) of the individual numbers: up to 1 kg per inner packaging and up to 12 kg per package;
  3. liquid substances that fall under c) of the individual numbers, up to 1 liter per inner packaging and up to 12 liters per package;
  4. solid substances falling under c) of the individual numbers: up to 2 kg per inner packaging. The total mass of the package may in no case exceed 20 kg. The "General Packaging Regulations" of marginal 3500 (1), (2) and (5) to (7) must be observed.

(3) Leak-proof batteries of number 81 (identification number 2800), if the electrolyte does not escape at a temperature of 55 ° C in the event of a housing breakage or a crack in the housing, there is no free liquid that can escape and the battery poles are protected against short circuits in packaging ready for dispatch.

(4)

  1. New batteries when:
    • they are secured against slipping, falling over and damage;
    • they are provided with carrying devices, except when the batteries are stacked on pallets, for example;
    • there are no dangerous traces of alkalis or acids on the outside of the objects;
    • they are secured against short circuits.
  2. Used batteries when:
    • their housings are not damaged;
    • they are secured against leaking, sliding, falling over and damage, e.g. stacked on pallets;
    • there are no dangerous traces of alkalis or acids on the outside of the objects;
    • they are secured against short circuits.

"Used batteries" are those that are transported for recycling purposes after normal use.

(5) Products and instruments that contain no more than 1 kg of mercury as specified in section 66 c).

(6) In the case of transport in accordance with paragraphs (1) and (2), each package must be clearly and permanently marked:

  1. with the identification number of the product, preceded by the letters "UN";
  2. for different goods with different identification numbers in one and the same package:
    • with the identification numbers of the filling goods, preceded by the letters "UN", or
    • with the letters "LQ".

This marking must be enclosed by a line forming an inverted square with a side of at least 100 mm; if the size of a package so requires, this marking may be smaller, provided it remains clearly visible.

2. Regulations

A. Packages

1. General packaging regulations

ADR 011, 2 - 2802

(1) The packaging must comply with the provisions of Annex A.5, unless special provisions for the packaging of certain substances are provided in marginal 2803 to 2808.

(2) The IBCs must comply with the provisions of Appendix A.6.

(3) According to the provisions of marginal 2800 (3) b) and 3511 (2) or 3611 (2), the following are to be used:

Packaging of packing group I, marked with the letter "X", or large packaging (IBC) of packing group I, marked with the letter "X", for highly corrosive substances that fall under letter a) of the individual numbers

  • Packagings of packing group II or I, marked with the letter "Y" or "X", or IBCs of packing group II or I, marked with the letter "Y" or "X", for corrosive substances under the letters b) the individual digits fall,
  • Packagings of packing group III, II or I or bulk packaging (IBC) of packing group III, II or I, marked with the letters "Z", "Y" or "X", for slightly corrosive substances listed under c) of the individual Digits fall.

    Note For the transport of substances of class 8 in tank vehicles, demountable tanks and tank containers as well as for the transport in bulk, see Appendix B.

2. Special packaging regulations

2803

The substances in number 6 must be packed in pressure receptacles made of carbon steel or suitable alloy steel. The following pressure vessels are permitted:

  1. Bottles with a capacity of 150 liters or less;
  2. Vessels with a capacity of at least 100 liters and a maximum of 1000 liters (e.g. cylindrical vessels with rolling hoops and vessels on sliding devices).

The pressure receptacles must comply with the relevant class 2 regulations (see marginal 2212, 2213, 2215 to 2217 and 2223).

The wall thickness of the pressure vessels must not be less than 3 mm.

Before they are used for the first time, the pressure vessels must be subjected to a fluid pressure test with a pressure of at least 1 MPB (10 bar) (overpressure). The pressure test must be repeated every 8 years and with an internal

Investigation of the pressure vessels as well as a check of the fittings to connect. In addition, the pressure vessels must be checked every 2 years for wear with suitable measuring devices (e.g. ultrasound) and for the condition of the fittings.

The tests and examinations are to be carried out under the control of an officially recognized expert. The maximum mass of the filling per liter of capacity is 0.84 kg.

2804

(1) Bromine and bromine, solutions of number 14 must be packed in inner packaging made of glass, the content of which must not exceed 2.5 liters per inner packaging, or in inner packaging made of polyvinyl difluoride (PVDF), the content of which must not exceed 15 liters per inner packaging which in turn are used in composite packagings as specified in marginal 3538. The assembled packaging must be tested and approved for packaging group I in accordance with Appendix A.5.

(2) Bromine with a water content of less than 0.005% or from 0.005 to 0.2%, if measures have been taken for the latter to prevent corrosion of the vessel lining, may also be carried in vessels which must meet the following conditions :

  1. the receptacles must be made of steel, tightly lined with lead or some other material providing the same protection and provided with an airtight seal; Vessels made of Monel alloys, nickel or with a nickel lining are also permitted;
  2. the capacity of the receptacles must not exceed 450 liters;
  3. the receptacles may be filled to a maximum of 92% of their capacity or a maximum of 2.86 kg per liter of capacity;
  4. the vessels must be welded and dimensioned for a calculation pressure of at least 2.1 MPa (21 bar) (overpressure). The material and design must also comply with the relevant class 2 regulations (see marginal 2212). For the initial inspection of the unlined steel vessels, the relevant regulations of class 2 apply (see marginal 2215 to 2217);
  5. the closure devices should protrude as little as possible over the surface of the vessel and must be provided with protective caps. These devices and the protective caps must be provided with seals that are insensitive to the corrosive effects of the bromine. The closures must be in the upper part of the vessel so that they cannot come into constant contact with the liquid phase;
  6. the vessels must be provided with devices that make it possible to place them securely on their baths. They must be provided with devices (rings, flanges, etc.) on their upper part, which enable them to be handled and which have been tested with twice the useful weight.

(3) Before they are used for the first time, the vessels in accordance with Paragraph (2) must be subjected to a leak test at a pressure of at least 200 kPa (2 bar) (excess pressure). This test must be repeated every two years and combined with an internal examination of the vessels and a check of the net weight. The leak test and the internal examination are to be carried out under the control of an officially recognized expert.

(4) The following must be clearly legible and indelible on the vessels according to paragraph (2):

  • the name or make of the manufacturer and the number of the receptacle;
  • the term "bromine";
  • the net weight of the receptacle and the maximum permissible mass of the filled receptacle;
  • the date (month, year) of the first and the most recently performed periodic test;
  • the stamp of the expert who carried out the tests.